Keeping intention to provide improved manufacturing process to synthesize aryl sulfonates from aryl halides by reducing the formation of process impurities to give good yields and reduce manufacturing cost. Literature says, Copper catalyzed Solfonation of the aryl halide to get aryl sulfones is very important reaction or conversion to the chemical industry. This research work was new and belongs to chemical research and development of process by changing parameters like temp, time, reagents etc., to improve the yield and quality of the product.