This work aims to study the metallic supramolecular ionic network of organic cation and anionic tetrachloroplatinate as well as anticancer chemistry of Pt (II) and (IV) complexes. This work describes the influence of ionic network and coordinates bonding on the DNA interaction activities of the complexes. It contains four chapters; first three chapters significantly reveal the work done and their importance, and the fourth chapter concludes all the aspects of work done.