SI-ATRP for Attaining Tailor-Made Polymer Coatings

Atom transfer radical polymerization initiated from a surface of various substrates (SI-ATRP) has become a progressively popular technique for obtaining thin polymer films with predetermined properties. The present work addresses the main features of SI-ATRP with respect to the controllability, rates of polymerization, suitable monomers, reaction mixture compositions etc. An alternative potential-driven polymerization approach is discussed, although to a smaller extent.